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Chemo-photothermal synergy ignites antitumor immunity via ferroptosis - PubMed

6 hours ago
  • #immunotherapy
  • #photothermal therapy
  • #ferroptosis
  • Development of amphiphilic ferrocene-based polymer (PPEGMA-b-PFMMA) to co-encapsulate Docetaxel (Doc) and photosensitizer IR808, forming photothermally responsive nanoparticles (P8D NPs).
  • P8D NPs improve aqueous stability and tumor-specific accumulation via hydrogen peroxide (H₂O₂)-triggered drug release in the tumor microenvironment.
  • Near-infrared (NIR) irradiation causes P8D NPs to generate heat and reactive oxygen species (ROS), promoting drug release and nanoparticle disintegration.
  • Doc induces HMGB1 translocation from nucleus to cytoplasm, while PTT/PDT facilitates extracellular release of DAMPs and tumor-associated antigens via ferroptosis and cell membrane rupture.
  • Enhanced dendritic cell (DC) maturation, antigen presentation, and cytotoxic CD8+ T cell infiltration reverse the immunosuppressive tumor microenvironment.
  • Combination strategy inhibits distant tumor growth and establishes long-term anti-tumor immunological memory to prevent recurrence.
  • Ferrocene-based nanocarrier-mediated PTT/PDT synergizes with Doc to reactivate antitumor immunity through ferroptosis-induced immunogenic cell death (ICD).