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Orbitals from Entanglement: Quantum Information gives rise to Chemical bonds

6 hours ago
  • #quantum chemistry
  • #quantum entanglement
  • #chemical bonding
  • Chemical bonding is a nonlocal phenomenon but lacks a universal definition.
  • This work uses orbital entanglement from quantum information theory to analyze bonding.
  • Maximally entangled atomic orbitals (MEAOs) capture both Lewis and beyond-Lewis structures.
  • Multipartite entanglement serves as an index of bond strength.
  • The framework applies to equilibrium geometries, transition states, and aromaticity.
  • It may bridge Hilbert space and real-space atomic partitioning methods.