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ROS-responsive self-assembly of baicalin-peptide as a "Molecular Latch" to break the endothelial-to-mesenchymal transition-inflammation loop in atherosclerotic plaques - PubMed

5 hours ago
  • #Atherosclerosis
  • #Peptide self-assembly
  • #Inflammation
  • ROS-responsive self-assembly of baicalin-peptide conjugate (VRBPC) targets atherosclerotic plaques.
  • VRBPC acts as a 'Molecular Latch' to disrupt the EndMT-inflammation loop in plaques.
  • Mechanism involves VCAM-1 targeting, ROS-triggered self-assembly, and HSP90 competitive binding by baicalin.
  • VRBPC inhibits Smad2/3 phosphorylation, reverses EndMT, and reduces inflammation in macrophages.
  • In vitro and in vivo studies show VRBPC restores endothelial function and stabilizes plaques with no systemic toxicity.
  • Offers a new approach for precision therapy in atherosclerosis and inflammatory vascular diseases.