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Oxygen-dependent dynamics of metformin biodegradation at the sediment-water interface and non-additive effects on prokaryotic communities - PubMed

19 days ago
  • #Metformin
  • #Biodegradation
  • #Prokaryotic communities
  • Metformin, an antidiabetic drug, is commonly found in aquatic environments due to incomplete removal during wastewater treatment.
  • The study examined metformin degradation and its effects on prokaryotic communities under different oxygenation conditions in sediment-water interface microcosms.
  • In autoclaved microcosms, metformin dissipated slowly without significant transformation products, regardless of oxygenation.
  • Biotic microcosms showed metformin biodegradation within 13 days, with faster degradation under anoxic conditions.
  • Guanylurea was the only detected transformation product, suggesting microbial use of metformin-derived compounds as carbon and nitrogen sources.
  • Prokaryotic community composition was influenced by oxygenation conditions and repeated metformin exposure, with both additive and non-additive effects observed.
  • Twenty-one bacterial taxonomic biomarkers of metformin exposure were identified, including methylotrophic taxa potentially utilizing metformin and its metabolites.
  • Microbial activity was crucial for metformin dissipation, and oxygenation conditions modulated its effects on prokaryotic communities.
  • The study highlights the importance of oxygenation and microbial responses in assessing pharmaceutical behavior and risks in dynamic aquatic environments.