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Advancing Targeted Protein Degradation Through Immunoproteasome-Caged N-Degrons - PubMed

7 hours ago
  • #Immunoproteasome
  • #PROTACs
  • #Targeted Protein Degradation
  • PROTACs are a promising therapeutic modality for targeted protein degradation but face limitations like metabolic instability and selectivity issues.
  • N-degron-based PROTACs are compact and effective but prone to premature degradation and off-target effects.
  • Loy et al. introduced a 'caged' N-degron PROTAC, shielded by a tetrapeptide-morpholine fragment, specifically recognized by the immunoproteasome (iCP).
  • The iCP is highly expressed in cancer and inflammatory cells but absent in most healthy tissues, allowing for context-dependent specificity.
  • Upon iCP-mediated cleavage, the degron is unmasked, enabling targeted degradation of ABL tyrosine kinase via dasatinib-linked PROTAC activity.
  • This strategy enhances functional stability and integrates endogenous proteolytic specificity into degrader activation.
  • Challenges remain regarding cell permeability and disease-dependent iCP expression.
  • Immunoproteasome-gated degron represents a compelling framework for next-generation N-degron PROTACs.