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Cryo-EM structures of UBA6 reveal mechanisms of E1-E2 specificity and dual FAT10/ubiquitin thioester transfer - PubMed

4 hours ago
  • #Proteostasis
  • #Cryo-EM
  • #Ubiquitin
  • Cryo-EM structures of UBA6 reveal mechanisms of E1-E2 specificity and dual FAT10/ubiquitin thioester transfer.
  • UBA1 and UBA6 define parallel ubiquitin (Ub) activation systems with non-overlapping roles in Ub and ubiquitin-like protein (Ubl) signaling.
  • UBA6 activates the Ubl FAT10, linking Ub signaling to immune-regulated proteostasis.
  • UBA6 achieves E2 specificity through coordinated contributions of the UFD and SCCH domains, contrasting with UBA1's UFD-dominated selectivity.
  • An inositol hexakisphosphate (InsP6)-binding site unique to UBA6 stabilizes an expanded SCCH cleft, pre-organizing the enzyme for selective E2 engagement.
  • The findings define principles for E1-E2 recognition and identify InsP6 as a cofactor in the Ub-like conjugation network.